Issue 29, 2013
From the journal:

Dalton Transactions

Reaction of Li/Cl phosphinidenoid complexes with a phosphite substituted ketone: access to complexes with a novel mixed-valence polycyclic P,C-ligand system†‡

Liliya Abdrakhmanova,a   Arturo Espinosa*b  and  Rainer Streubel*c  

* Corresponding authors

a A. E. Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Centre of the Russian Academy of Sciences, A.E. Arbuzov Str. 8, 420088 Kazan, Russian Federation
E-mail: liliyaam@mail.ru
Fax: +7 8432 755322
Tel: +7 8432 727384

b Departamento de Química Orgánica. Facultad de Química. Universidad de Murcia, Campus de Espinardo, 30100 Murcia, Spain
E-mail: artuesp@um.es
Fax: +34 868 88 4149
Tel: +34 868 88 7489

c Institut für Anorganische Chemie der Rheinischen Friedrich-Wilhelms-Universität Bonn, Gerhard-Domagk-Str. 1, D-53121 Bonn, Germany
E-mail: r.streubel@uni-bonn.de
Fax: +49-228-739616
Tel: +49-228-735345

Abstract

Reaction of Li/Cl phosphinidenoid pentacarbonyltungsten(0) complexes 2a,b (R = CH(SiMe3)2, Cp*) with bifunctional phosphite-substituted ketone 3 yielded tungsten complexes 4a,b having a novel mixed-valence polycyclic P,C-cage ligand with a P–P bond. DFT calculations provide insight into an unusual product formation pathway.

Graphical abstract: Reaction of Li/Cl phosphinidenoid complexes with a phosphite substituted ketone: access to complexes with a novel mixed-valence polycyclic P,C-ligand system

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Article information

DOI
https://doi.org/10.1039/C3DT50902H
Article type
Paper
Submitted
04 Apr 2013
Accepted
29 May 2013
First published
30 May 2013

Dalton Trans., 2013,42, 10510-10514

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Reaction of Li/Cl phosphinidenoid complexes with a phosphite substituted ketone: access to complexes with a novel mixed-valence polycyclic P,C-ligand system

L. Abdrakhmanova, A. Espinosa and R. Streubel, Dalton Trans., 2013, 42, 10510 DOI: 10.1039/C3DT50902H

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