Issue 36, 2013
From the journal:

Dalton Transactions

Modified boron subphthalocyanines with stable electrochemistry and tuneable bandgaps†

Brett A. Kaminoa  and  Timothy P. Bender*abc  

* Corresponding authors

a Department of Chemical Engineering and Applied Chemistry, 200 College St., Toronto, Ontario, Canada

b Department of Chemistry, 80 St. George St., Toronto, Ontario, Canada

c Department of Materials Science and Engineering, 180 College St., Toronto, Ontario, Canada
E-mail: tim.bender@utoronto.ca

Abstract

The synthesis of boron subphthalocyanines (BsubPc) from modified phthalonitriles is reported. The BsubPcs have intense red-shifted absorption compared to normal BsubPcs and readily tuneable optoelectronic properties including enhanced electrochemical stability and the presence of up to two reversible electrochemical reductions.

Graphical abstract: Modified boron subphthalocyanines with stable electrochemistry and tuneable bandgaps

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Article information

DOI
https://doi.org/10.1039/C3DT50615K
Article type
Paper
Submitted
24 Jun 2013
Accepted
04 Jul 2013
First published
04 Jul 2013

Dalton Trans., 2013,42, 13145-13150

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Modified boron subphthalocyanines with stable electrochemistry and tuneable bandgaps

B. A. Kamino and T. P. Bender, Dalton Trans., 2013, 42, 13145 DOI: 10.1039/C3DT50615K

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