Issue 13, 2013
From the journal:

Dalton Transactions

Iron vs. cobalt clathrochelate electrocatalysts of HER: the first example on a cage iron complex†

Alexander V. Dolganov,a   Alexander S. Belov,a   Valentin V. Novikov,a   Anna V. Vologzhanina,a   Andriy Mokhir,b   Yurii N. Bubnova  and  Yan Z. Voloshin*a  

* Corresponding authors

a Nesmeyanov Institute of Organoelement Compounds RAS, 119991 Moscow, Russia
E-mail: voloshin@ineos.ac.ru
Fax: +7 (499)135-5085

b University of Erlangen-Nürnberg, Department of Chemistry and Pharmacy, Organic Chemistry II, 91054 Erlangen, Germany

Abstract

New macrobicyclic 2-thiopheneboron-capped iron and cobalt(II) tris-dioximates showed high electrocatalytic activity for hydrogen production from H+ ions. This is the first example of the hydrogen evolution reaction electrocatalyzed by a clathrochelate iron complex, which catalyzes the hydrogen production at low overpotential.

Graphical abstract: Iron vs. cobalt clathrochelate electrocatalysts of HER: the first example on a cage iron complex

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Article information

DOI
https://doi.org/10.1039/C3DT33073G
Article type
Communication
Submitted
21 Dec 2012
Accepted
05 Feb 2013
First published
06 Feb 2013

Dalton Trans., 2013,42, 4373-4376

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Iron vs. cobalt clathrochelate electrocatalysts of HER: the first example on a cage iron complex

A. V. Dolganov, A. S. Belov, V. V. Novikov, A. V. Vologzhanina, A. Mokhir, Y. N. Bubnov and Y. Z. Voloshin, Dalton Trans., 2013, 42, 4373 DOI: 10.1039/C3DT33073G

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