Issue 21, 2013
From the journal:

Dalton Transactions

Catalytic isomerization of allylic alcohols in water by [RuClCp(PTA)2], [RuClCp(HPTA)2]Cl2·2H2O, [RuCp(DMSO-κS)(PTA)2]Cl, [RuCp(DMSO-κS)(PTA)2](OSO2CF3) and [RuCp(DMSO-κS)(HPTA)2]Cl3·2H2O†

Manuel Serrano-Ruiz,a   Pablo Lorenzo-Luis,b   Antonio Romerosa*a  and  Adrian Mena-Cruzb  

* Corresponding authors

a Área de Química Inorgánica, Facultad de Ciencias, Universidad de Almería, Almería, Spain
E-mail: romerosa@ual.es
Fax: +34 950015008

b Departamento de Química Inorgánica, Facultad de Química, Universidad de La Laguna, La Laguna, Tenerife, Spain

Abstract

The new water soluble complexes [RuClCp(HPTA)2]Cl2·2H2O (2), [RuCp(DMSO-κS)(PTA)2]Cl (3), [RuCp(DMSO-κS)(PTA)2](OSO2CF3) (4) and [RuCp(DMSO-κS)(HPTA)2]Cl3·2H2O (5) have been synthesized and fully characterized by NMR, IR and elemental analysis. The structures of complexes 2·2H22O and 5·2H22O were also characterized by single crystal X-ray determination. The catalytic activity of the complexes and [RuClCp(PTA)2] (1) for the isomerisation in water of 1-octen- to 1-penten-3-ol was assessed and discussed.

Graphical abstract: Catalytic isomerization of allylic alcohols in water by [RuClCp(PTA)2], [RuClCp(HPTA)2]Cl2·2H2O, [RuCp(DMSO-κS)(PTA)2]Cl, [RuCp(DMSO-κS)(PTA)2](OSO2CF3) and [RuCp(DMSO-κS)(HPTA)2]Cl3·2H2O

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Article information

DOI
https://doi.org/10.1039/C3DT32998D
Article type
Paper
Submitted
13 Dec 2012
Accepted
23 Feb 2013
First published
26 Feb 2013

Dalton Trans., 2013,42, 7622-7630

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Catalytic isomerization of allylic alcohols in water by [RuClCp(PTA)2], [RuClCp(HPTA)2]Cl2·2H2O, [RuCp(DMSO-κS)(PTA)2]Cl, [RuCp(DMSO-κS)(PTA)2](OSO2CF3) and [RuCp(DMSO-κS)(HPTA)2]Cl3·2H2O

M. Serrano-Ruiz, P. Lorenzo-Luis, A. Romerosa and A. Mena-Cruz, Dalton Trans., 2013, 42, 7622 DOI: 10.1039/C3DT32998D

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