Issue 4, 2013
From the journal:

Dalton Transactions

An unusual seven-connected lead borate constructed by different cluster building units of {B6} and {Pb6}†

Han-Rui Tian,a   Wen-Hua Wang,a   Xiao-Ping Zhang,a   Yun-Long Fenga  and  Jian-Wen Cheng*a  

* Corresponding authors

a Key Laboratory of the Ministry of Education for Advanced Catalysis Materials, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang, P.R. China
E-mail: jwcheng@zjnu.cn

Abstract

A new 3D lead borate Pb6B6O14(OH)2(H2O), built by different cluster building units of B6O14(OH) {B6} and Pb6O5(OH) {Pb6}, has been obtained under mild hydrothermal conditions. Each {B6} cluster is linked with seven {Pb6} clusters and vice versa that give rise to the first 7-connected lead borate network.

Graphical abstract: An unusual seven-connected lead borate constructed by different cluster building units of {B6} and {Pb6}

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Article information

DOI
https://doi.org/10.1039/C2DT32364H
Article type
Communication
Submitted
06 Oct 2012
Accepted
11 Nov 2012
First published
15 Nov 2012

Dalton Trans., 2013,42, 894-897

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An unusual seven-connected lead borate constructed by different cluster building units of {B6} and {Pb6}

H. Tian, W. Wang, X. Zhang, Y. Feng and J. Cheng, Dalton Trans., 2013, 42, 894 DOI: 10.1039/C2DT32364H

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