Palladium ketonyl carboxylate complexes – potential models of polynuclear intermediates in olefin oxidation: formation and X-ray structure of Pd6(μ-Cl)2+x(μ-CF3CO2)4(μ,κ2-CH2C(O)CMe3)6−x (x = 0, 2)

Oleg N. Shishilov; Roman E. Podobedov; Yaroslavna N. Rezinkova; Andrei V. Churakov; Inessa A. Efimenko

doi:10.1039/C2DT31824E

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Palladium ketonyl carboxylate complexes – potential models of polynuclear intermediates in olefin oxidation: formation and X-ray structure of Pd₆(μ-Cl)_2+x(μ-CF₃CO₂)₄(μ,κ²-CH₂C(O)CMe₃)_6−x (x = 0, 2)†

Oleg N. Shishilov,*^a Roman E. Podobedov,^a Yaroslavna N. Rezinkova,^a Andrei V. Churakov^a and Inessa A. Efimenko^a

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^a Leninsky pr., 31, Moscow, Russia
E-mail: oshishilov@gmail.com
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Abstract

Reactions of Pd₄(NO)₄(CF₃CO₂)₄ with olefins were studied, this Pd-cluster was shown to promote the oxidation of olefins into ketones, which were found as ketonyl ligands in complex products of the reaction; 6-nuclear palladium clusters with carboxylate and ketonyl ligands Pd₆(μ-Cl)_x(μ-CF₃CO₂)₄(μ,κ²-CH₂C(O)CMe₃)_6−x were characterized by XRD analysis.

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Supplementary files

Crystal structure data TXT (42K)

Article information

DOI: https://doi.org/10.1039/C2DT31824E
Article type: Communication
Submitted: 10 Aug 2012
Accepted: 21 Nov 2012
First published: 22 Nov 2012

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Dalton Trans., 2013,42, 1338-1341

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Palladium ketonyl carboxylate complexes – potential models of polynuclear intermediates in olefin oxidation: formation and X-ray structure of Pd₆(μ-Cl)_2+x(μ-CF₃CO₂)₄(μ,κ²-CH₂C(O)CMe₃)_6−x (x = 0, 2)

O. N. Shishilov, R. E. Podobedov, Y. N. Rezinkova, A. V. Churakov and I. A. Efimenko, Dalton Trans., 2013, 42, 1338 DOI: 10.1039/C2DT31824E

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Dalton Transactions