Issue 19, 2013
From the journal:

Physical Chemistry Chemical Physics

Overcoming the shortcomings of the Nernst–Planck model

Wolfgang Dreyer,a   Clemens Guhlkea  and  Rüdiger Müller*a  

* Corresponding authors

a Weierstrass-Institute, Mohrenstr. 39, 10117 Berlin, Germany
E-mail: wolfgang.dreyer@wias-berlin.de, clemens.guhlke@wias-berlin.de, ruediger.mueller@wias-berlin.de

Abstract

This is a study on electrolytes that takes a thermodynamically consistent coupling between mechanics and diffusion into account. It removes some inherent deficiencies of the popular Nernst–Planck model. A boundary problem for equilibrium processes is used to illustrate the features of the new model.

Graphical abstract: Overcoming the shortcomings of the Nernst–Planck model

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Article information

DOI
https://doi.org/10.1039/C3CP44390F
Article type
Paper
Submitted
06 Dec 2012
Accepted
15 Mar 2013
First published
04 Apr 2013

Phys. Chem. Chem. Phys., 2013,15, 7075-7086

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Overcoming the shortcomings of the Nernst–Planck model

W. Dreyer, C. Guhlke and R. Müller, Phys. Chem. Chem. Phys., 2013, 15, 7075 DOI: 10.1039/C3CP44390F

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