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Issue 33, 2013
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Two chiral multinuclear palladium(II) complexes comprising alternately arranged isomerous hexanuclear clusters

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Abstract

Two new chiral hexanuclear palladium(II) complexes [Pd6(Cys)4(CysH)4][Pd6(CysH)8]Cl4·24H2O (1) and [Pd6(HCys)10](NO3)2·11H2O (2) are prepared through careful control of the reaction conditions. Both complexes comprise two alternately arranged isomerous hexanuclear Pd(II) clusters. As supported by ESI-MS spectra and CD analyses, the integrity of the structures can be maintained in aqueous solution and the chirality of L-Cys ligands can be preserved to the multinuclear Pd complexes.

Graphical abstract: Two chiral multinuclear palladium(ii) complexes comprising alternately arranged isomerous hexanuclear clusters

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Publication details

The article was received on 02 May 2013, accepted on 13 Jun 2013 and first published on 14 Jun 2013


Article type: Communication
DOI: 10.1039/C3CE40773J
Citation: CrystEngComm, 2013,15, 6461-6464

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    Two chiral multinuclear palladium(II) complexes comprising alternately arranged isomerous hexanuclear clusters

    Z. Lin, B. Chen, X. Feng, B. Wang, Y. Chi, Y. Fan, X. Yang, X. Huang and C. Hu, CrystEngComm, 2013, 15, 6461
    DOI: 10.1039/C3CE40773J

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