Issue 33, 2013

Two chiral multinuclear palladium(ii) complexes comprising alternately arranged isomerous hexanuclear clusters

Abstract

Two new chiral hexanuclear palladium(II) complexes [Pd6(Cys)4(CysH)4][Pd6(CysH)8]Cl4·24H2O (1) and [Pd6(HCys)10](NO3)2·11H2O (2) are prepared through careful control of the reaction conditions. Both complexes comprise two alternately arranged isomerous hexanuclear Pd(II) clusters. As supported by ESI-MS spectra and CD analyses, the integrity of the structures can be maintained in aqueous solution and the chirality of L-Cys ligands can be preserved to the multinuclear Pd complexes.

Graphical abstract: Two chiral multinuclear palladium(ii) complexes comprising alternately arranged isomerous hexanuclear clusters

Supplementary files

Article information

Article type
Communication
Submitted
02 May 2013
Accepted
13 Jun 2013
First published
14 Jun 2013

CrystEngComm, 2013,15, 6461-6464

Two chiral multinuclear palladium(II) complexes comprising alternately arranged isomerous hexanuclear clusters

Z. Lin, B. Chen, X. Feng, B. Wang, Y. Chi, Y. Fan, X. Yang, X. Huang and C. Hu, CrystEngComm, 2013, 15, 6461 DOI: 10.1039/C3CE40773J

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