Issue 48, 2013
From the journal:

CrystEngComm

Renaissance of the coordination chemistry of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT). Part I: First crystal structure of a TPymT complex with a d-metal cation†

Damir A. Safin,a   Yang Xu,a   Ilia Korobkov,a   David L. Brycea  and  Muralee Murugesu*a  

* Corresponding authors

a Department of Chemistry, University of Ottawa, 10 Marie Curie Private, Ottawa, ON, Canada K1N 6N5
E-mail: m.murugesu@uottawa.ca
Fax: +1 613 562 5170
Tel: +1 613 562 5800 ext. 2733

Abstract

An unprecedented dinuclear heteroleptic CdII complex was isolated using a stable multidentate 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) ligand, which can be seen as a triply fused terpyridine ligand. In the obtained complex, TPymT retains its structural integrity without undergoing oft-observed hydrolysis.

Graphical abstract: Renaissance of the coordination chemistry of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT). Part I: First crystal structure of a TPymT complex with a d-metal cation

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Article information

DOI
https://doi.org/10.1039/C3CE42146E
Article type
Communication
Submitted
23 Oct 2013
Accepted
28 Oct 2013
First published
29 Oct 2013

CrystEngComm, 2013,15, 10419-10422

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Renaissance of the coordination chemistry of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT). Part I: First crystal structure of a TPymT complex with a d-metal cation

D. A. Safin, Y. Xu, I. Korobkov, D. L. Bryce and M. Murugesu, CrystEngComm, 2013, 15, 10419 DOI: 10.1039/C3CE42146E

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