Issue 48, 2013

Renaissance of the coordination chemistry of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT). Part I: First crystal structure of a TPymT complex with a d-metal cation

Abstract

An unprecedented dinuclear heteroleptic CdII complex was isolated using a stable multidentate 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT) ligand, which can be seen as a triply fused terpyridine ligand. In the obtained complex, TPymT retains its structural integrity without undergoing oft-observed hydrolysis.

Graphical abstract: Renaissance of the coordination chemistry of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT). Part I: First crystal structure of a TPymT complex with a d-metal cation

Supplementary files

Article information

Article type
Communication
Submitted
23 Oct 2013
Accepted
28 Oct 2013
First published
29 Oct 2013

CrystEngComm, 2013,15, 10419-10422

Renaissance of the coordination chemistry of 2,4,6-tris(2-pyrimidyl)-1,3,5-triazine (TPymT). Part I: First crystal structure of a TPymT complex with a d-metal cation

D. A. Safin, Y. Xu, I. Korobkov, D. L. Bryce and M. Murugesu, CrystEngComm, 2013, 15, 10419 DOI: 10.1039/C3CE42146E

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