Issue 47, 2013
From the journal:

CrystEngComm

Battlement-shaped 1D coordination polymer based on a bis(N-methylimidazole-2-yl)butadiyne ligand†

Thomas Waidmann,a   Nico Fritsch,a   Johannes Tucher,a   Marc Rudolf,b   Felix Glaser,a   Dirk M. Guldi*b  and  Nicolai Burzlaff*a  

* Corresponding authors

a Department of Chemistry and Pharmacy, University of Erlangen-Nürnberg, Egerlandstrasse 1, 91058 Erlangen, Germany
E-mail: nicolai.burzlaff@fau.de
Fax: +49 9131 85 27387
Tel: +49 9131 85 28976

b Department of Chemistry and Pharmacy, University of Erlangen-Nürnberg, Egerlandstrasse 3, 91058 Erlangen, Germany
E-mail: dirk.guldi@fau.de
Fax: +49 9131 85 27341
Tel: +49 9131 85 28307

Abstract

Bis(N-methylimidazole-2-yl)butadiyne (bmib) has been prepared starting from N-methylimidazole following two different pathways. Bmib fluoresces and is capable of forming 1D coordination polymers by clamping together metal units. The molecular structure of a zinc coordination polymer based on bmib and zinc acetate resembles a battlement of a fortress.

Graphical abstract: Battlement-shaped 1D coordination polymer based on a bis(N-methylimidazole-2-yl)butadiyne ligand

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Article information

DOI
https://doi.org/10.1039/C3CE41652F
Article type
Communication
Submitted
12 Jul 2013
Accepted
21 Aug 2013
First published
21 Aug 2013
This article is Open Access
Creative Commons BY license

CrystEngComm, 2013,15, 10157-10160

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Battlement-shaped 1D coordination polymer based on a bis(N-methylimidazole-2-yl)butadiyne ligand

T. Waidmann, N. Fritsch, J. Tucher, M. Rudolf, F. Glaser, D. M. Guldi and N. Burzlaff, CrystEngComm, 2013, 15, 10157 DOI: 10.1039/C3CE41652F

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