Trication-templated assembly of POMs resulted in an unprecedented ι-type octamolybdate configuration. The ι-[Mo8O26]4− cluster is composed of five {MoO6} octahedra and three {MoO4} tetrahedra via an edge-sharing and corner-sharing arrangement to form a cabas-like cluster, which represents the ninth isomer of octamolybdates.
![Graphical abstract: An unprecedented ι-type octamolybdate: [TbI1]2[(β-Mo8O26)0.5(ι-Mo8O26)] directed by a new tricationic template](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C3CE41418C&imageInfo.ImageIdentifier.Year=2013)
Z. Yue, H. Du, Y. Niu and G. Jin, CrystEngComm, 2013, 15, 9844 DOI: 10.1039/C3CE41418C
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