Issue 46, 2013
From the journal:

CrystEngComm

Solid state photodimerisation of tetrathiafulvalene derivatives bearing carboxylate and carboxylic acid substituents†

Claudia Simao,‡a   Marta Mas-Torrent,a   Vânia André,b   M. Teresa Duarte,b   Simone Techert,cd   Jaume Vecianaa  and  Concepció Rovira*a  

* Corresponding authors

a Institut de Ciència de Materials de Barcelona (ICMAB-CSIC) and Networking Research Center on Bioengineering, Biomaterials and Nanomedicine (CIBER-BBN), Campus Universitario de Bellaterra, Cerdanyola, Barcelona, Spain
E-mail: cun@icmab.es
Fax: +34 935805729
Tel: +34 931888786

b Centro de Química Estrutural, Instituto Superior Técnico, Universidade Técnica de Lisboa, Av. Rovisco Pais, 1049-001 Lisbon, Portugal

c IFG Structural Dynamics of (Bio)chemical Systems, Max Planck Institute for Biophysical Chemistry, 37070 Göttingen, Germany

d Deutsches Elektronensynchrotron DESY, Notkestrasse 85, 22607 Hamburg, Germany

Abstract

Structural and spectroscopic studies on the [2+2] photodimerisation of TTF derivatives show that solid state cycloaddition leads to a dimer with a face-to-face structure. The type of phototransformation of the material depends not only on the optical characteristics of the reactant but also on those of the product.

Graphical abstract: Solid state photodimerisation of tetrathiafulvalene derivatives bearing carboxylate and carboxylic acid substituents

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Article information

DOI
https://doi.org/10.1039/C3CE41353E
Article type
Communication
Submitted
10 Jul 2013
Accepted
27 Sep 2013
First published
02 Oct 2013

CrystEngComm, 2013,15, 9878-9884

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Solid state photodimerisation of tetrathiafulvalene derivatives bearing carboxylate and carboxylic acid substituents

C. Simao, M. Mas-Torrent, V. André, M. Teresa Duarte, S. Techert, J. Veciana and C. Rovira, CrystEngComm, 2013, 15, 9878 DOI: 10.1039/C3CE41353E

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