Issue 28, 2013
From the journal:

CrystEngComm

Homochiral crystallization of single-stranded helical coordination polymers: generated by the structure of auxiliary ligands or spontaneous symmetry breaking†

Shuai Ding,a   Yanfei Gao,a   Yufei Ji,a   Yanqin Wanga  and  Zhiliang Liu*a  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Key Laboratory of Nanomagnetic and Functional Materials, Inner Mongolia University, Hohhot, P. R. China
E-mail: cezlliu@imu.edu.cn
Fax: +86 471 4992147
Tel: +86 471 4995414

Abstract

Homochiral crystallizations of single-stranded helical coordination polymers were constructed using the V-shaped bridging ligand dicyanamide (μ1,5-dca−) and chelate auxiliary ligands. The enantiomeric nature of 1 and 2 is directly induced by the chirality of the auxiliary ligands. Whereas, the homochirality feature for 3 stems from the spontaneous symmetry breaking in crystallization.

Graphical abstract: Homochiral crystallization of single-stranded helical coordination polymers: generated by the structure of auxiliary ligands or spontaneous symmetry breaking

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CE40519B
Article type
Communication
Submitted
24 Mar 2013
Accepted
11 May 2013
First published
13 May 2013

CrystEngComm, 2013,15, 5598-5601

Permissions

Request permissions

Homochiral crystallization of single-stranded helical coordination polymers: generated by the structure of auxiliary ligands or spontaneous symmetry breaking

S. Ding, Y. Gao, Y. Ji, Y. Wang and Z. Liu, CrystEngComm, 2013, 15, 5598 DOI: 10.1039/C3CE40519B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements