A novel 3-D chiral polyoxovanadate architecture based on breaking high symmetry of spherical [V15O36Cl]8− cluster

Jian Zhou; Xing Liu; Feilong Hu; Rong Chen; Huahong Zou; Wensheng Fu; Guoming Liang; Yi Chen

doi:10.1039/C3CE40280K

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A novel 3-D chiral polyoxovanadate architecture based on breaking high symmetry of spherical [V₁₅O₃₆Cl]⁸⁻ cluster†

Jian Zhou,*^ab Xing Liu,^a Feilong Hu,^b Rong Chen,^a Huahong Zou,^c Wensheng Fu,^a Guoming Liang^a and Yi Chen^b

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* Corresponding authors

^a College of Chemistry, Chongqing Normal University, Chongqing 401331, P. R. China
E-mail: Jianzhou888888@163.com, Jianzhou888888@yahoo.com.cn
Fax: +86-023-65419972
Tel: +86-023-65419972

^b College of Chemistry and Material, Yulin Normal University, Yulin 537000, P. R. China

^c Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Ministry of Education of China), School of Chemistry and Chemical Engineering of Guangxi Normal University, Guilin 541004, P. R. China

Abstract

A novel 3-D chiral polyoxovanadate {[Zn(en)₂]₂V₁₅O₃₆Cl}[Zn(en)₂(H₂O)]₂·3H₂O (1, en = ethylenediamine) has been hydrothermally synthesized under spontaneous resolution without any chiral source. The unique 3-D chiral architecture of 1 is built up from destroying high symmetry of the spherical [V₁₅O₃₆Cl]⁸⁻ cluster. Magnetic measurements illustrate that 1 has antiferromagnetic exchange interactions between metal centers.

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Article information

DOI: https://doi.org/10.1039/C3CE40280K
Article type: Communication
Submitted: 13 Feb 2013
Accepted: 04 Apr 2013
First published: 04 Apr 2013

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CrystEngComm, 2013,15, 4593-4596

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A novel 3-D chiral polyoxovanadate architecture based on breaking high symmetry of spherical [V₁₅O₃₆Cl]⁸⁻ cluster

J. Zhou, X. Liu, F. Hu, R. Chen, H. Zou, W. Fu, G. Liang and Y. Chen, CrystEngComm, 2013, 15, 4593 DOI: 10.1039/C3CE40280K

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