Issue 18, 2013

Intermolecular hydrogen bonds directed tetramer and intramolecular electronic communication: paramagnetic di([5]trovacenyl)arsinous acid§

Abstract

Paramagnetic di([5]trovacenyl)arsinous acid was prepared and characterized by X-ray crystallography, cyclic voltammetry, EPR spectroscopy and magnetic susceptometry. A weak intramolecular electronic communication is observed. XRD demonstrates an intermolecular hydrogen bonds directed tetramer. It represents the first structural characterization of organometallic arsinous acid.

Graphical abstract: Intermolecular hydrogen bonds directed tetramer and intramolecular electronic communication: paramagnetic di([5]trovacenyl)arsinous acid

Supplementary files

Article information

Article type
Communication
Submitted
05 Feb 2013
Accepted
14 Mar 2013
First published
14 Mar 2013

CrystEngComm, 2013,15, 3525-3528

Intermolecular hydrogen bonds directed tetramer and intramolecular electronic communication: paramagnetic di([5]trovacenyl)arsinous acid

C. Elschenbroich, F. Lu, K. Harms and C. Pietzonka, CrystEngComm, 2013, 15, 3525 DOI: 10.1039/C3CE40246K

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