Metal–organic framework architecture with polyhedron-in-polyhedron and further polyhedral assembly†
Abstract
Presented here is a polyhedral building architecture of a porous MOF containing polyhedron-in-polyhedron subunits, in which a cube based on unusual CuII3(CN)(COO)3 clusters is situated in the core of a sodalite cage with 24 paddle-wheel Cu2(COO)4 units.