Issue 3, 2013
From the journal:

CrystEngComm

A new strategy for the construction of a single-walled metal–organic nanotubular framework: utilizing “T”-shaped building unit with ligand modification†

Bao-Yu Liu,a   Feng Liu,a   Li-Hong Lv,a   Javier Grajedaa  and  Xiao-Chun Huang*a  

* Corresponding authors

a Department of Chemistry, Shantou University, Guangdong, P. R. China
E-mail: xchuang@stu.edu.cn
Fax: +86-0754-82902767
Tel: +86-0754-82902589

Abstract

Two coordination compounds, Cu(pim) (1) and Cu2(ppt)·1.5H2O (2) (Hpim = 2-(4-pyridyl)-imidazole, H2ppt = 5-(4-pyridyl)-1H-1,2,4-triazole-3-thiol), based on ligands with a “T”-shaped structural unit were reported here. 1 presents a 2D layer network, whereas 2 shows a MOF containing a 1D tubular channel, which are constructed utilizing a similar unit to the 2D layer in 1, representing a new strategy to construct tubular frameworks. Furthermore, basic properties such as photoluminescence and gas adsorption have been investigated as well.

Graphical abstract: A new strategy for the construction of a single-walled metal–organic nanotubular framework: utilizing “T”-shaped building unit with ligand modification

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Article information

DOI
https://doi.org/10.1039/C2CE26350E
Article type
Communication
Submitted
22 Aug 2012
Accepted
31 Oct 2012
First published
01 Nov 2012

CrystEngComm, 2013,15, 447-450

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A new strategy for the construction of a single-walled metal–organic nanotubular framework: utilizing “T”-shaped building unit with ligand modification

B. Liu, F. Liu, L. Lv, J. Grajeda and X. Huang, CrystEngComm, 2013, 15, 447 DOI: 10.1039/C2CE26350E

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