A H2DABCO templated copper(I) chloride framework of the stoichiometry [Cu16Cl22]6− formed from linked CuCl4, CuCl3 and CuCl2 units crystallizes in a non-centrosymmetric space group.
![Graphical abstract: Hydrothermal synthesis and structural characterisation of [H2DABCO]3[Cu16Cl22]: a new copper(i) chloride framework](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C2CE26068A&imageInfo.ImageIdentifier.Year=2013)
E. R. Williams and M. T. Weller, CrystEngComm, 2013, 15, 31 DOI: 10.1039/C2CE26068A
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