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Issue 94, 2013
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On the chemical reactions of carbon dioxide isoelectronic molecules CS2 and OCS with 1-butyl-3-methylimidazolium acetate

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Abstract

Raman and NMR spectroscopies show that CS2 and OCS react spontaneously with 1-butyl-3-methylimidazolium acetate [C4mim] [Ac] in the liquid phase. The formation of [C4mim] CO2, [C4mim] COS, CH3COS and gaseous CO2 and OCS in both systems demonstrates that the anion plays an unexpected role not observed in the CO2–[C4mim] [Ac] reaction.

Graphical abstract: On the chemical reactions of carbon dioxide isoelectronic molecules CS2 and OCS with 1-butyl-3-methylimidazolium acetate

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Publication details

The article was received on 07 Aug 2013, accepted on 08 Oct 2013 and first published on 08 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC46038J
Citation: Chem. Commun., 2013,49, 11083-11085

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    On the chemical reactions of carbon dioxide isoelectronic molecules CS2 and OCS with 1-butyl-3-methylimidazolium acetate

    M. Isabel Cabaço, M. Besnard, F. V. Chávez, N. Pinaud, P. J. Sebastião, J. A. P. Coutinho, J. Mascetti and Y. Danten, Chem. Commun., 2013, 49, 11083
    DOI: 10.1039/C3CC46038J

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