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Issue 74, 2013
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“Click” dendrimers as efficient nanoreactors in aqueous solvent: Pd nanoparticle stabilization for sub-ppm Pd catalysis of Suzuki–Miyaura reactions of aryl bromides

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Abstract

Palladium nanoparticles (PdNPs) with a size of 1.4 nm are stabilized by dendritic nanoreactors containing 1,2,3-triazole ligands with hydrophilic triethylene glycol (TEG) termini. These PdNPs are stable for months under air and are extremely active for the Suzuki–Miyaura reactions of aryl bromides down to sub-ppm levels.

Graphical abstract: “Click” dendrimers as efficient nanoreactors in aqueous solvent: Pd nanoparticle stabilization for sub-ppm Pd catalysis of Suzuki–Miyaura reactions of aryl bromides

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Publication details

The article was received on 08 Jul 2013, accepted on 19 Jul 2013 and first published on 22 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC45132A
Citation: Chem. Commun., 2013,49, 8169-8171
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    “Click” dendrimers as efficient nanoreactors in aqueous solvent: Pd nanoparticle stabilization for sub-ppm Pd catalysis of Suzuki–Miyaura reactions of aryl bromides

    C. Deraedt, L. Salmon, L. Etienne, J. Ruiz and D. Astruc, Chem. Commun., 2013, 49, 8169
    DOI: 10.1039/C3CC45132A

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