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Issue 79, 2013
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Synthesis and properties of boron complexes of [14]triphyrins(2.1.1)

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Abstract

Boron complexes of [14]triphyrins(2.1.1) were prepared from free-base [14]triphyrins(2.1.1) with phenylboron dichloride. The absorption spectrum of the meso-free β-alkyl–triphyrin boron complex in CH2Cl2 showed a broad weak band at around 640 nm assigned to transition from B-phenyl to the triphyrin, while that of the meso-aryl benzotriphyrin boron complex showed only Soret and Q bands.

Graphical abstract: Synthesis and properties of boron complexes of [14]triphyrins(2.1.1)

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Publication details

The article was received on 26 Jun 2013, accepted on 04 Aug 2013 and first published on 21 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC44788J
Citation: Chem. Commun., 2013,49, 8955-8957
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    Synthesis and properties of boron complexes of [14]triphyrins(2.1.1)

    D. Kuzuhara, Z. Xue, S. Mori, T. Okujima, H. Uno, N. Aratani and H. Yamada, Chem. Commun., 2013, 49, 8955
    DOI: 10.1039/C3CC44788J

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