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Issue 75, 2013
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P-chirogenic organocatalysts: application to the aza-Morita–Baylis–Hillman (aza-MBH) reaction of ketimines

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Abstract

The P-chirogenic organocatalysts were found to promote the enantioselective aza-Morita–Baylis–Hillman reaction of ketimines derived from acyclic α-keto esters. In the P-chirogenic organocatalyzed aza-MBH reactions, α,α-disubstituted α-amino acid derivatives were obtained in high yields with high enantioselectivities (up to 97% ee).

Graphical abstract: P-chirogenic organocatalysts: application to the aza-Morita–Baylis–Hillman (aza-MBH) reaction of ketimines

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Article information


Submitted
18 Jun 2013
Accepted
19 Jul 2013
First published
22 Jul 2013

Chem. Commun., 2013,49, 8392-8394
Article type
Communication

P-chirogenic organocatalysts: application to the aza-Morita–Baylis–Hillman (aza-MBH) reaction of ketimines

S. Takizawa, E. Rémond, F. A. Arteaga, Y. Yoshida, V. Sridharan, J. Bayardon, S. Jugé and H. Sasai, Chem. Commun., 2013, 49, 8392
DOI: 10.1039/C3CC44549F

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