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Issue 96, 2013
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Modular structure of a robust microporous MOF based on Cu2 paddle-wheels with high CO2 selectivity

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Abstract

The synthesis of a new MOF with Cu2 paddle-wheels connected to glutarate and 1,3-bis(4-pyridyl)propane linkers has been explored. Experimental gas adsorption measurements reveal that the MOF is essentially non-porous to methane whereas it presents a type III isotherm upon CO2 adsorption, leading to high capacity and outstanding CO2 selectivity.

Graphical abstract: Modular structure of a robust microporous MOF based on Cu2 paddle-wheels with high CO2 selectivity

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Publication details

The article was received on 04 Jun 2013, accepted on 08 Oct 2013 and first published on 10 Oct 2013


Article type: Communication
DOI: 10.1039/C3CC44193H
Chem. Commun., 2013,49, 11329-11331

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    Modular structure of a robust microporous MOF based on Cu2 paddle-wheels with high CO2 selectivity

    J. M. Seco, D. Fairen-Jimenez, A. J. Calahorro, L. Méndez-Liñán, M. Pérez-Mendoza, N. Casati, E. Colacio and A. Rodríguez-Diéguez, Chem. Commun., 2013, 49, 11329
    DOI: 10.1039/C3CC44193H

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