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Issue 74, 2013
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A bifunctional palladium/acid solid catalyst performs the direct synthesis of cyclohexylanilines and dicyclohexylamines from nitrobenzenes

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Abstract

Nitroderivatives are transformed to cyclohexylanilines at room temperature in good yields and selectivity via a hydrogenation-amine coupling cascade reaction using Pd nanoparticles on carbon as a catalyst and a Brönsted acid.

Graphical abstract: A bifunctional palladium/acid solid catalyst performs the direct synthesis of cyclohexylanilines and dicyclohexylamines from nitrobenzenes

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Publication details

The article was received on 30 May 2013, accepted on 17 Jul 2013 and first published on 18 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC44064H
Citation: Chem. Commun., 2013,49, 8160-8162
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    A bifunctional palladium/acid solid catalyst performs the direct synthesis of cyclohexylanilines and dicyclohexylamines from nitrobenzenes

    P. Rubio-Marqués, A. Leyva-Pérez and A. Corma, Chem. Commun., 2013, 49, 8160
    DOI: 10.1039/C3CC44064H

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