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Issue 67, 2013
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Ionic conductivity of [Li+@C60](PF6) in organic solvents and its electrochemical reduction to Li+@C60˙

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Abstract

The ionic conductivity of [Li+@C60](PF6) was measured in o-dichlorobenzene, and found to be higher than that of TBA+PF6. Electrochemical reduction of [Li+@C60](PF6) without any supporting electrolyte gave the monovalent radical anion Li+@C60˙, as confirmed by the characteristic ESR signal and NIR absorption band.

Graphical abstract: Ionic conductivity of [Li+@C60](PF6−) in organic solvents and its electrochemical reduction to Li+@C60˙−

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Article information


Submitted
24 May 2013
Accepted
26 Jun 2013
First published
27 Jun 2013

This article is Open Access

Chem. Commun., 2013,49, 7376-7378
Article type
Communication

Ionic conductivity of [Li+@C60](PF6) in organic solvents and its electrochemical reduction to Li+@C60˙

H. Ueno, K. Kokubo, Y. Nakamura, K. Ohkubo, N. Ikuma, H. Moriyama, S. Fukuzumi and T. Oshima, Chem. Commun., 2013, 49, 7376
DOI: 10.1039/C3CC43901A

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