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Issue 71, 2013
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Catalytic asymmetric exo-selective [6+3] cycloaddition of iminoesters with fulvenes

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Abstract

A novel exo-selective [6+3] cycloaddition approach for the highly enantioselective synthesis of polysubstituted piperidines was developed. The developed methodology was applied in a one-pot [6+3]–[4+2] dicycloaddition, allowing the construction of structurally and stereochemically rich polycyclic compounds from simple building blocks.

Graphical abstract: Catalytic asymmetric exo-selective [6+3] cycloaddition of iminoesters with fulvenes

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Publication details

The article was received on 21 May 2013, accepted on 02 Jul 2013 and first published on 03 Jul 2013


Article type: Communication
DOI: 10.1039/C3CC43824D
Citation: Chem. Commun., 2013,49, 7800-7802
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    Catalytic asymmetric exo-selective [6+3] cycloaddition of iminoesters with fulvenes

    M. Potowski, A. P. Antonchick and H. Waldmann, Chem. Commun., 2013, 49, 7800
    DOI: 10.1039/C3CC43824D

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