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Issue 59, 2013
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Preorganized assembly of three iron(ii) or manganese(ii) β-diketiminate complexes using a cyclophane ligand

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Abstract

A trinucleating cyclophane bearing three β-diketimine arms, and the corresponding iron(II) and manganese(II) complexes have been synthesized and characterized. The three metal ions are oriented towards the internal void space, and are coordinated by a N2Br2 donor set, in which a unique combination of μ3, μ, and terminal coordination modes are observed for the halide donors.

Graphical abstract: Preorganized assembly of three iron(ii) or manganese(ii) β-diketiminate complexes using a cyclophane ligand

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Article information


Submitted
07 May 2013
Accepted
06 Jun 2013
First published
17 Jun 2013

Chem. Commun., 2013,49, 6635-6637
Article type
Communication

Preorganized assembly of three iron(II) or manganese(II) β-diketiminate complexes using a cyclophane ligand

G. L. Guillet, F. T. Sloane, D. M. Ermert, M. W. Calkins, M. K. Peprah, E. S. Knowles, E. Čižmár, K. A. Abboud, M. W. Meisel and L. J. Murray, Chem. Commun., 2013, 49, 6635
DOI: 10.1039/C3CC43395A

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