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Issue 59, 2013
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Preorganized assembly of three iron(II) or manganese(II) β-diketiminate complexes using a cyclophane ligand

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Abstract

A trinucleating cyclophane bearing three β-diketimine arms, and the corresponding iron(II) and manganese(II) complexes have been synthesized and characterized. The three metal ions are oriented towards the internal void space, and are coordinated by a N2Br2 donor set, in which a unique combination of μ3, μ, and terminal coordination modes are observed for the halide donors.

Graphical abstract: Preorganized assembly of three iron(ii) or manganese(ii) β-diketiminate complexes using a cyclophane ligand

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Publication details

The article was received on 07 May 2013, accepted on 06 Jun 2013 and first published on 17 Jun 2013


Article type: Communication
DOI: 10.1039/C3CC43395A
Citation: Chem. Commun., 2013,49, 6635-6637

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    Preorganized assembly of three iron(II) or manganese(II) β-diketiminate complexes using a cyclophane ligand

    G. L. Guillet, F. T. Sloane, D. M. Ermert, M. W. Calkins, M. K. Peprah, E. S. Knowles, E. Čižmár, K. A. Abboud, M. W. Meisel and L. J. Murray, Chem. Commun., 2013, 49, 6635
    DOI: 10.1039/C3CC43395A

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