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Issue 56, 2013
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Ferromagnetic superexchange in a 1D –[LaIII–radical]– coordination polymer

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Abstract

The first coordination polymer of a bridging radical 1,2,3,5-dithiadiazolyl ligand is reported. Upon coordination with the La(hfac)3 fragment, the paramagnetic 4-(benzoxazol-2′-yl)-1,2,3,5-dithiadiazolyl (boaDTDA) ligand forms a one-dimensional (1D) alternating –[La(hfac)3–boaDTDA]npolymer exhibiting ferromagnetic (FM) coupling between the radicals, mediated through the diamagnetic LaIII ion (hfac = 1,1,1,5,5,5-hexafluoroacetylacetonato).

Graphical abstract: Ferromagnetic superexchange in a 1D –[LaIII–radical]– coordination polymer

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Article information


Submitted
02 May 2013
Accepted
24 May 2013
First published
28 May 2013

Chem. Commun., 2013,49, 6271-6273
Article type
Communication

Ferromagnetic superexchange in a 1D –[LaIII–radical]– coordination polymer

E. M. Fatila, R. Clérac, M. Rouzières, D. V. Soldatov, M. Jennings and K. E. Preuss, Chem. Commun., 2013, 49, 6271
DOI: 10.1039/C3CC43267J

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