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Issue 38, 2013
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Diastereoselective synthesis of meso-pillar[6]arenes by bridging between hydroquinone units in an alternating up-and-down manner

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Abstract

We report the first synthesis of bridged pillararenes. Meso-form pillar[6]arenes were diastereo-selectively formed by bridging units of a per-hydroxylated pillar[6]arene in an alternating up-and-down manner with dialkyldichlorosilanes.

Graphical abstract: Diastereoselective synthesis of meso-pillar[6]arenes by bridging between hydroquinone units in an alternating up-and-down manner

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Publication details

The article was received on 02 Mar 2013, accepted on 26 Mar 2013 and first published on 26 Mar 2013


Article type: Communication
DOI: 10.1039/C3CC41592A
Chem. Commun., 2013,49, 3952-3954

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    Diastereoselective synthesis of meso-pillar[6]arenes by bridging between hydroquinone units in an alternating up-and-down manner

    T. Ogoshi, K. Demachi, K. Masaki and T. Yamagishi, Chem. Commun., 2013, 49, 3952
    DOI: 10.1039/C3CC41592A

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