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Issue 24, 2013
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Anion-ordered chains in a d1 perovskite oxynitride: NdVO2N

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Abstract

The correlated anion order in the oxynitride perovskite NdVO2N, where disordered zig-zag VN chains segregate into planes within a pseudo-cubic lattice, is similar to that in materials such as SrTaO2N containing d0 transition metal cations. However, NdVO2N has 3d1 V4+ cations and the 3d-electrons are itinerant, showing that the anion chain order in oxynitride perovskites is robust to electron-doping.

Graphical abstract: Anion-ordered chains in a d1 perovskite oxynitride: NdVO2N

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Publication details

The article was received on 05 Dec 2012, accepted on 05 Feb 2013 and first published on 06 Feb 2013


Article type: Communication
DOI: 10.1039/C3CC38736D
Citation: Chem. Commun., 2013,49, 2430-2432
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    Anion-ordered chains in a d1 perovskite oxynitride: NdVO2N

    J. Oró-Solé, L. Clark, W. Bonin, J. P. Attfield and A. Fuertes, Chem. Commun., 2013, 49, 2430
    DOI: 10.1039/C3CC38736D

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