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Issue 16, 2013
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Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution

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Abstract

Pillar substitution in a long-known metal–organic material with saturated metal centres, [Cu(bipy)2(SiF6)]n, has afforded the first crystallographically characterized porous materials based upon TiF62− and SnF62− anions as pillars. Gas adsorption studies revealed similar surface areas and adsorption isotherms but enhanced selectivity towards CO2vs. CH4 and N2.

Graphical abstract: Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution

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Article information


Submitted
22 Oct 2012
Accepted
08 Jan 2013
First published
09 Jan 2013

Chem. Commun., 2013,49, 1606-1608
Article type
Communication

Enhancement of CO2 selectivity in a pillared pcu MOM platform through pillar substitution

P. Nugent, V. Rhodus, T. Pham, B. Tudor, K. Forrest, L. Wojtas, B. Space and M. Zaworotko, Chem. Commun., 2013, 49, 1606
DOI: 10.1039/C3CC37695H

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