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Issue 61, 2013
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A PdAg bimetallic nanocatalyst for selective reductive amination of nitroarenes

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Abstract

Herein we have identified an optimal catalyst, Pd1Ag1.7, for the tandem reductive amination between nitroarenes and aldehydes (selectivity > 93%). Key to the success is the ability to control the compositions of the investigational Pd1−xAgx (x = 0–1) catalysts, as well as the clear composition dependent activity/selectivity trend observed in this study. This catalyst features a wide substrate scope, excellent recyclability, activity and selectivity under ambient conditions.

Graphical abstract: A PdAg bimetallic nanocatalyst for selective reductive amination of nitroarenes

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Supplementary files

Article information


Submitted
11 Jan 2013
Accepted
28 Feb 2013
First published
07 Mar 2013

Chem. Commun., 2013,49, 6843-6845
Article type
Communication

A PdAg bimetallic nanocatalyst for selective reductive amination of nitroarenes

L. Li, Z. Niu, S. Cai, Y. Zhi, H. Li, H. Rong, L. Liu, L. Liu, W. He and Y. Li, Chem. Commun., 2013, 49, 6843
DOI: 10.1039/C3CC00249G

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