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Issue 36, 2013
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Large shape-persistent metal-invertible 15-Nsp2-donor-atom macrocycles functioning as trinucleating ligands

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Abstract

Reaction of 4,6-dihydrazinopyrimidines with 2,6-dicarbonylpyridines produces, under metal-free or template conditions, a new class of [3 + 3] macrocycles with 15 Nsp2 donor atoms. Nine Nsp2 atoms are on the external circumference of the macrocycle. The macrocycle can bind metal ions and produce trinuclear complexes along with the motion of the nine outer Nsp2 atoms to inner positions (a motion of inversion of the macrocycle).

Graphical abstract: Large shape-persistent metal-invertible 15-Nsp2-donor-atom macrocycles functioning as trinucleating ligands

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Publication details

The article was received on 04 Oct 2012, accepted on 14 Dec 2012 and first published on 02 Apr 2013


Article type: Communication
DOI: 10.1039/C2CC37260F
Citation: Chem. Commun., 2013,49, 3784-3786

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    Large shape-persistent metal-invertible 15-Nsp2-donor-atom macrocycles functioning as trinucleating ligands

    A. Stadler, J. Jiang, H. Wang and C. Bailly, Chem. Commun., 2013, 49, 3784
    DOI: 10.1039/C2CC37260F

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