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Issue 39, 2013
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Synthesis and structure of a hydrogenated zinc hemiporphyrazine

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Abstract

Palladium-catalyzed hydrogenation of an octahedral zinc trans-ditriflate hemiporphyrazine “HpH2Zn(OTf)2” furnishes a new macrocycle “HpH6Zn(OTf)2”. This reaction is fully reversible upon heating in nitrobenzene, and the conversion is easily monitored by changes in color and fluorescence properties. The reversible cycling between these molecules may find future applications in hemiporphyrazine-based catalysts and/or hydrogen storage devices.

Graphical abstract: Synthesis and structure of a hydrogenated zinc hemiporphyrazine

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Article information


Submitted
01 Oct 2012
Accepted
05 Nov 2012
First published
06 Nov 2012

Chem. Commun., 2013,49, 4280-4282
Article type
Communication

Synthesis and structure of a hydrogenated zinc hemiporphyrazine

S. M. Huber, G. Mata, A. Linden and N. W. Luedtke, Chem. Commun., 2013, 49, 4280
DOI: 10.1039/C2CC37151K

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