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Issue 100, 2013
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C–H functionalization of tetramethylsilane employing a borylnitrene

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Abstract

The irradiation of 2-azido-4,4,5,5-tetramethyl-1,3,2-dioxaborol (pinBN3, pin = pinacolato) generates the corresponding borylnitrene that easily inserts into the CH bond of tetramethylsilane. This primary photoproduct, a monoborylated aminoborane, undergoes a subsequent reaction with pinBN3 forming a bisborylated aminoborane.

Graphical abstract: C–H functionalization of tetramethylsilane employing a borylnitrene

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Submitted
09 Oct 2013
Accepted
18 Oct 2013
First published
08 Nov 2013

Chem. Commun., 2013,49, 11773-11775
Article type
Communication

C–H functionalization of tetramethylsilane employing a borylnitrene

M. Müller, C. Maichle-Mössmer and H. F. Bettinger, Chem. Commun., 2013, 49, 11773
DOI: 10.1039/C3CC47753C

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