Issue 96, 2013
From the journal:

Chemical Communications

A chiral open-framework fluoroaluminophosphate with enantiomeric excess in the bulk product†

Xiaoqiang Tong,a   Wenfu Yan,*a   Jihong Yua  and  Ruren Xua  

* Corresponding authors

a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, PR China
E-mail: yanw@jlu.edu.cn
Fax: +86-431-85168609
Tel: +86-431-85168609

Abstract

A novel chiral open-framework fluoroaluminophosphate [C4N3H16][Al6P3O12F6(OH)6] was hydrothermally synthesized using diethylenetriamine as a structure-directing agent. The significant enantiomeric excess of the bulk product was confirmed by the solid state vibrational circular dichroism (VCD) spectrum.

Graphical abstract: A chiral open-framework fluoroaluminophosphate with enantiomeric excess in the bulk product

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Article information

DOI
https://doi.org/10.1039/C3CC47241H
Article type
Communication
Submitted
22 Sep 2013
Accepted
09 Oct 2013
First published
10 Oct 2013

Chem. Commun., 2013,49, 11287-11289

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A chiral open-framework fluoroaluminophosphate with enantiomeric excess in the bulk product

X. Tong, W. Yan, J. Yu and R. Xu, Chem. Commun., 2013, 49, 11287 DOI: 10.1039/C3CC47241H

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