Issue 94, 2013
From the journal:

Chemical Communications

Copper nanoparticle-catalyzed cross-coupling of alkyl halides with Grignard reagents†

Ju Hyun Kima  and  Young Keun Chung*a  

* Corresponding authors

a Intelligent Textile System Research Center, and Department of Chemistry, College of Natural Sciences, Seoul National University, Seoul, Korea
E-mail: ykchung@snu.ac.kr
Fax: +82-2-889-0310

Abstract

A cross-coupling reaction between alkyl bromides and chlorides and various Grignard reagents was carried out in the presence of commercially available copper or copper oxide nanoparticles as a catalyst and an alkyne additive. The catalytic system shows high activity, a broad scope, and good functional group tolerance.

Graphical abstract: Copper nanoparticle-catalyzed cross-coupling of alkyl halides with Grignard reagents

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Article information

DOI
https://doi.org/10.1039/C3CC46419A
Article type
Communication
Submitted
22 Aug 2013
Accepted
08 Oct 2013
First published
08 Oct 2013

Chem. Commun., 2013,49, 11101-11103

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Copper nanoparticle-catalyzed cross-coupling of alkyl halides with Grignard reagents

J. H. Kim and Y. K. Chung, Chem. Commun., 2013, 49, 11101 DOI: 10.1039/C3CC46419A

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