Issue 86, 2013
From the journal:

Chemical Communications

Pressure accelerated 1,3-dipolar cycloaddition of azide and alkyne groups in crystals†

Ben-Bo Ni,a   Kai Wang,b   Qifan Yan,a   Hao Chen,a   Yuguo Ma*a  and  Bo Zou*b  

* Corresponding authors

a Beijing National Laboratory for Molecular Sciences (BNLMS), Key Lab of Polymer Chemistry & Physics of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China
E-mail: ygma@pku.edu.cn

b State Key Laboratory of Superhard Materials, Jilin University, Changchun 130012, China
E-mail: zoubo@jlu.edu.cn
Fax: +86 431 85168883

Abstract

The cycloaddition of azides and alkynes in the solid state was accelerated by high pressure. In situ Raman scattering and synchrotron X-ray diffraction were employed to study reaction kinetics at different pressures which revealed that the pressure acceleration originates from the elevated substrate energy and decreased activation energy.

Graphical abstract: Pressure accelerated 1,3-dipolar cycloaddition of azide and alkyne groups in crystals

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Article information

DOI
https://doi.org/10.1039/C3CC46153J
Article type
Communication
Submitted
12 Aug 2013
Accepted
02 Sep 2013
First published
02 Sep 2013

Chem. Commun., 2013,49, 10130-10132

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Pressure accelerated 1,3-dipolar cycloaddition of azide and alkyne groups in crystals

B. Ni, K. Wang, Q. Yan, H. Chen, Y. Ma and B. Zou, Chem. Commun., 2013, 49, 10130 DOI: 10.1039/C3CC46153J

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