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Issue 81, 2013
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Electrophilic fluorination using a hypervalent iodine reagent derived from fluoride

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Abstract

The air and moisture stable fluoroiodane 8, readily prepared on a 6 g scale by nucleophilic fluorination of the hydroxyiodane 7 with TREAT-HF, has been used as an electrophilic fluorinating reagent for the first time to monofluorinate 1,3-ketoesters and difluorinate 1,3-diketones in good isolated yields.

Graphical abstract: Electrophilic fluorination using a hypervalent iodine reagent derived from fluoride

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Supplementary files

Article information


Submitted
26 Jun 2013
Accepted
15 Aug 2013
First published
16 Aug 2013

Chem. Commun., 2013,49, 9263-9265
Article type
Communication

Electrophilic fluorination using a hypervalent iodine reagent derived from fluoride

G. C. Geary, E. G. Hope, K. Singh and A. M. Stuart, Chem. Commun., 2013, 49, 9263
DOI: 10.1039/C3CC44792H

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