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Issue 74, 2013
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Palladium-catalyzed oxidative direct C–H/C–H cross coupling of anilides with β-keto esters

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Abstract

A Pd(II)-catalyzed oxidative direct C(sp2)–H/C(sp3)–H cross coupling of anilides with α-dicarbonyl compounds with Mn(OAc)3·2H2O as the oxidant is reported and this protocol provides facile access to α-aryl malonates and β-keto esters in good yields and regioselectivity.

Graphical abstract: Palladium-catalyzed oxidative direct C–H/C–H cross coupling of anilides with β-keto esters

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Supplementary files

Article information


Submitted
25 Jun 2013
Accepted
15 Jul 2013
First published
16 Jul 2013

Chem. Commun., 2013,49, 8214-8216
Article type
Communication

Palladium-catalyzed oxidative direct C–H/C–H cross coupling of anilides with β-keto esters

W. Chan, Z. Zhou and W. Yu, Chem. Commun., 2013, 49, 8214
DOI: 10.1039/C3CC44769C

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