Room temperature C–H bond activation on a [PdI–PdI] platform

Mithun Sarkar; Henri Doucet; Jitendra K. Bera

doi:10.1039/C3CC44493G

You do not have JavaScript enabled. Please enable JavaScript to access the full features of the site or access our non-JavaScript page.

Room temperature C–H bond activation on a [Pd^I–Pd^I] platform†

Mithun Sarkar,^a Henri Doucet^b and Jitendra K. Bera*^a

Author affiliations

* Corresponding authors

^a Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016, India
E-mail: jbera@iitk.ac.in
Fax: +91-512-2597436
Tel: +91-512-2597336

^b Institut Sciences Chimiques de Rennes, UMR 6226 CNRS Université de Rennes, “Catalyse et Organometalliques”, Campus de Beaulieu, 35042 Rennes, France

Abstract

Heteroatom assisted C–H bond activation of 2-substituted naphthyridines with solvated Pd^I₂(CH₃CN)₆(BF₄)₂ provides bi- and trinuclear Pd^II cyclometalated complexes, which provide valuable insight into potential intermediates in palladium catalyzed direct arylation reactions.

Download options Please wait...

Supplementary files

Article information

DOI: https://doi.org/10.1039/C3CC44493G
Article type: Communication
Submitted: 15 Jun 2013
Accepted: 27 Aug 2013
First published: 28 Aug 2013

Download Citation

Chem. Commun., 2013,49, 9764-9766

Permissions

Request permissions

Room temperature C–H bond activation on a [Pd^I–Pd^I] platform

M. Sarkar, H. Doucet and J. K. Bera, Chem. Commun., 2013, 49, 9764 DOI: 10.1039/C3CC44493G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Social activity

Fetching data from CrossRef.
This may take some time to load.

Chemical Communications