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Issue 79, 2013
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Halogen bond induced phosphorescence of capped γ-amino acid in the solid state

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Abstract

The Boc and N,N′-dicyclohexylurea capped γ-amino acid upon monobromination showed phosphorescence in the solid state. The compound exhibited different photoluminescence intensity and lifetimes in crystals obtained from ethyl acetate and methanol. X-ray crystallography revealed that the intermolecular C[double bond, length as m-dash]O…Br halogen bond directs the heavy atom effect to produce the phosphorescence.

Graphical abstract: Halogen bond induced phosphorescence of capped γ-amino acid in the solid state

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Publication details

The article was received on 05 Jun 2013, accepted on 07 Aug 2013 and first published on 08 Aug 2013


Article type: Communication
DOI: 10.1039/C3CC44231D
Citation: Chem. Commun., 2013,49, 9051-9053

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    Halogen bond induced phosphorescence of capped γ-amino acid in the solid state

    S. K. Maity, S. Bera, A. Paikar, A. Pramanik and D. Haldar, Chem. Commun., 2013, 49, 9051
    DOI: 10.1039/C3CC44231D

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