Issue 70, 2013
From the journal:

Chemical Communications

Oximate metal complexes breaking the limiting esterolytic reactivity of oximate anions†

Paola Gómez-Tagle,a   José Carlos Lugo-Gonzáleza  and  Anatoly K. Yatsimirsky*a  

* Corresponding authors

a Universidad Nacional Autónoma de México, Facultad de Química, Mexico City, Mexico
E-mail: anatoli@unam.mx
Fax: +52 55 56162010
Tel: +52 55 56223813

Abstract

Zinc(II) and cadmium(II) complexes of a tridentate oximate ligand cleave 4-nitrophenyl acetate with rate constants surpassing by two orders of magnitude those reported as the maximum possible level for highly basic free oximate anions as a result of removal of the “solvational imbalance” of the nucleophile by metal coordination.

Graphical abstract: Oximate metal complexes breaking the limiting esterolytic reactivity of oximate anions

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Article information

DOI
https://doi.org/10.1039/C3CC43944E
Article type
Communication
Submitted
25 May 2013
Accepted
11 Jul 2013
First published
12 Jul 2013

Chem. Commun., 2013,49, 7717-7719

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Oximate metal complexes breaking the limiting esterolytic reactivity of oximate anions

P. Gómez-Tagle, J. C. Lugo-González and A. K. Yatsimirsky, Chem. Commun., 2013, 49, 7717 DOI: 10.1039/C3CC43944E

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