Issue 62, 2013
From the journal:

Chemical Communications

Sensing of the concentration and enantiomeric excess of chiral compounds with tropos ligand derived metal complexes†

Peng Zhanga  and  Christian Wolf*a  

* Corresponding authors

a Department of Chemistry, Georgetown University, Washington, DC 20057, USA
E-mail: cw27@georgetown.edu
Fax: +1 202 687 6209
Tel: +1 202 687 3468

Abstract

Palladium(II) complexes carrying chromophoric tropos ligands show a characteristic UV change and strong Cotton effects upon coordination of amino alcohols or diamines. The distinct (chir)optical responses can be used for instantaneous in situ determination of the concentration and ee of diamines and amino alcohols at low concentrations.

Graphical abstract: Sensing of the concentration and enantiomeric excess of chiral compounds with tropos ligand derived metal complexes

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Article information

DOI
https://doi.org/10.1039/C3CC43653E
Article type
Communication
Submitted
15 May 2013
Accepted
13 Jun 2013
First published
13 Jun 2013

Chem. Commun., 2013,49, 7010-7012

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Sensing of the concentration and enantiomeric excess of chiral compounds with tropos ligand derived metal complexes

P. Zhang and C. Wolf, Chem. Commun., 2013, 49, 7010 DOI: 10.1039/C3CC43653E

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