Issue 64, 2013

Reversible carbon–carbon bond formation between carbonyl compounds and a ruthenium pincer complex

Abstract

This communication describes the reversible reaction of a ruthenium pincer complex with a variety of carbonyl compounds. Both NMR spectroscopic and X-ray crystallographic characterization of isomeric carbonyl adducts are reported, and the equilibrium constants for carbonyl binding have been determined.

Graphical abstract: Reversible carbon–carbon bond formation between carbonyl compounds and a ruthenium pincer complex

Supplementary files

Article information

Article type
Communication
Submitted
10 May 2013
Accepted
21 Jun 2013
First published
05 Jul 2013

Chem. Commun., 2013,49, 7147-7149

Reversible carbon–carbon bond formation between carbonyl compounds and a ruthenium pincer complex

C. A. Huff, J. W. Kampf and M. S. Sanford, Chem. Commun., 2013, 49, 7147 DOI: 10.1039/C3CC43517B

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