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Issue 75, 2013
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One-pot direct C–H arylation of arenes in water catalysed by RuCl3·nH2O–NaOAc in the presence of Zn

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Abstract

The inexpensive and commercially available catalytic system RuCl3·nH2O–NaOAc–Zn is active in water for the direct C–H arylation of arenes with aryl/heteroaryl chlorides. The reaction can be accelerated by the use of microwave irradiation and can also be scaled up to a multi-gram scale with excellent isolated yields.

Graphical abstract: One-pot direct C–H arylation of arenes in water catalysed by RuCl3·nH2O–NaOAc in the presence of Zn

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Article information


Submitted
09 May 2013
Accepted
05 Jun 2013
First published
07 Jun 2013

Chem. Commun., 2013,49, 8320-8322
Article type
Communication

One-pot direct C–H arylation of arenes in water catalysed by RuCl3·nH2O–NaOAc in the presence of Zn

L. A. Adrio, J. Gimeno and C. Vicent, Chem. Commun., 2013, 49, 8320
DOI: 10.1039/C3CC43452D

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