Issue 69, 2013
From the journal:

Chemical Communications

Fast transport of HCl across a hydrophobic layer over macroscopic distances by using a Pt(ii) compound as the transporter†‡

Antonino Giannetto,a   Santo Lanza,a   Fausto Puntoriero,a   Massimiliano Cordaroa  and  Sebastiano Campagna*a  

* Corresponding authors

a Dipartimento di Scienze Chimiche, Università di Messina, Via F. Stagno d'Alcontres 31, 98166 Messina, Italy
E-mail: campagna@unime.it

Abstract

[Pt(H-(ethyl)2-dithiooxamidate)2] plays the role of a HCl symporter, allowing fast HCl transport over macroscopic distances (cm scale) across a hydrophobic layer made of a chloroform solution, without any stirring. The process is limited by interfacial transfer, whereas HCl is transported within the hydrophobic phase at extremely high rates.

Graphical abstract: Fast transport of HCl across a hydrophobic layer over macroscopic distances by using a Pt(ii) compound as the transporter

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Article information

DOI
https://doi.org/10.1039/C3CC43355B
Article type
Communication
Submitted
06 May 2013
Accepted
27 Jun 2013
First published
28 Jun 2013

Chem. Commun., 2013,49, 7611-7613

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Fast transport of HCl across a hydrophobic layer over macroscopic distances by using a Pt(II) compound as the transporter

A. Giannetto, S. Lanza, F. Puntoriero, M. Cordaro and S. Campagna, Chem. Commun., 2013, 49, 7611 DOI: 10.1039/C3CC43355B

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