Issue 63, 2013
From the journal:

Chemical Communications

Effect of ligand geometry on selective gas-adsorption: the case of a microporous cadmium metal organic framework with a V-shaped linker†

Anna M. Plonka,‡a   Debasis Banerjee,‡b   William R. Woerner,a   Zhijuan Zhang,b   Jing Li*b  and  John B. Parise*ac  

* Corresponding authors

a Department of Geosciences, Stony Brook University, Stony Brook, NY 11794-2100, USA
E-mail: john.parise@stonybrook.edu
Fax: +1 631-632-8240

b Department of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, New Jersey, USA
E-mail: Jingli@rutgers.edu
Fax: +1-732-445-5312

c Photon Sciences Division, Brookhaven National Laboratory, Upton, NY, USA

Abstract

A microporous cadmium metal organic framework is synthesized and structurally characterized. The material possesses a 3-D framework with a 1-D sinusoidal chain and shows high selectivity for CO2 over N2. The selectivity is attributed to CO2 interacting with two phenyl rings of a V-shaped linker as estimated by the in situ XRD-DSC study.

Graphical abstract: Effect of ligand geometry on selective gas-adsorption: the case of a microporous cadmium metal organic framework with a V-shaped linker

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Article information

DOI
https://doi.org/10.1039/C3CC43299H
Article type
Communication
Submitted
03 May 2013
Accepted
12 Jun 2013
First published
12 Jun 2013

Chem. Commun., 2013,49, 7055-7057

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Effect of ligand geometry on selective gas-adsorption: the case of a microporous cadmium metal organic framework with a V-shaped linker

A. M. Plonka, D. Banerjee, W. R. Woerner, Z. Zhang, J. Li and J. B. Parise, Chem. Commun., 2013, 49, 7055 DOI: 10.1039/C3CC43299H

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