Issue 58, 2013
From the journal:

Chemical Communications

Oxidative alkoxycarbonylation of terminal alkenes with carbazates†

Yu-Han Su,a   Zhao Wua  and  Shi-Kai Tian*ab  

* Corresponding authors

a Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, China
E-mail: tiansk@ustc.edu.cn
Fax: +86 551-6360-1592
Tel: +86 551-6360-0871

b Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

Abstract

A range of terminal alkenes smoothly underwent palladium-catalyzed oxidative alkoxycarbonylation with carbazates under an oxygen atmosphere to afford structurally diverse α,β-unsaturated esters in moderate to good yields with excellent regioselectivity and E selectivity.

Graphical abstract: Oxidative alkoxycarbonylation of terminal alkenes with carbazates

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Article information

DOI
https://doi.org/10.1039/C3CC42994F
Article type
Communication
Submitted
23 Apr 2013
Accepted
14 May 2013
First published
31 May 2013

Chem. Commun., 2013,49, 6528-6530

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Oxidative alkoxycarbonylation of terminal alkenes with carbazates

Y. Su, Z. Wu and S. Tian, Chem. Commun., 2013, 49, 6528 DOI: 10.1039/C3CC42994F

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