Issue 57, 2013
From the journal:

Chemical Communications

Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(i) catalyzed 1,4-addition of aryl boronic acids to cyclic enones†‡

Qian Chen,*a   Chao Chen,a   Fang Guoa  and  Wujiong Xia*a  

* Corresponding authors

a State Key Lab of Urban Water Resource and Environment (SKLUWRE) & Academy of Fundamental and Interdisciplinary Science, Harbin Institute of Technology, Harbin, Heilongjiang, P. R. China
E-mail: chenqian@hit.edu.cn, xiawj@hit.edu.cn
Fax: +86-451-86403760
Tel: +86-451-86403193

Abstract

Chiral N-tert-butylsulfinyl vinyl aziridine ligands prepared from a readily available (R)-tert-butanesulfinamide have been applied in the rhodium-catalyzed asymmetric 1,4-addition of aryl boronic acids to cyclic enones, which gives high yields and excellent enantioselectivities.

Graphical abstract: Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(i) catalyzed 1,4-addition of aryl boronic acids to cyclic enones

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Article information

DOI
https://doi.org/10.1039/C3CC42673D
Article type
Communication
Submitted
12 Apr 2013
Accepted
29 May 2013
First published
30 May 2013

Chem. Commun., 2013,49, 6433-6435

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Application of chiral N-tert-butylsulfinyl vinyl aziridines in Rh(I) catalyzed 1,4-addition of aryl boronic acids to cyclic enones

Q. Chen, C. Chen, F. Guo and W. Xia, Chem. Commun., 2013, 49, 6433 DOI: 10.1039/C3CC42673D

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